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赵俊伟


作者:  时间:2017-05-29 15:22 

姓名:赵俊伟(博士)系别:化学系职称:河南大学特聘教授,博士生导师院内行政职务: 化学系副主任电话:0371-23881589传真:0371-23881589邮箱:zhaojunwei@henu.edu.cn

  • 个人简介

  • 研究方向及讲授课程

  • 研究成果

主要教育经历:

1998.9-2002.7 河南大学 化学 本科

2002.9-2005.7 河南大学 无机化学 硕士

2005.9-2008.7 中国科学院福建物质结构研究所 无机化学 博士

2010.1-2012.6 河南大学化学博士后流动站 无机化学 博士后

主要学术经历:

2008.7-2010.10 河南大学化学化工学院 讲师

2010.10-2014.11 河南大学化学化工学院 副教授

2014.11-至今 河南大学化学化工学院 教授

2016.3-至今 河南大学化学化工学院 河南大学特聘教授

2012.7 河南省高等学校青年骨干教师

2015.6 河南省教育厅学术技术带头人

2015.11 河南省高校科技创新人才获得者

2016.1 河南省科技创新人才杰出青年基金获得者

研究方向:

(1) 新型多金属氧酸盐功能材料的合成与制备化学及其发光及光催化、电学、磁性、铁电等物理化学性能研究

(2) 手性分子基功能材料的制备及手性识别、手性催化、光学活性、铁电压电及非线性光学研究

(3) 孤对电子空间效应诱导的簇合物的设计合成、溶液化学行为、质子导电及细胞药物活性的研究

相关研究成果在J. Am. Chem. Soc. Chem. Commun., Chem. Eur. J., Chem. Asian J.; Inorg. Chem. , Cryst. Growth Des., Dalton Trans., CrystEngComm, Eur. J. Inorg. Chem., J. Solid State Chem.等国外知名杂志上发表学术论文90余篇。

讲授课程:

主要担任本科生《无机化学》、《无机化学实验》、《无机及分析化学实验》和研究生《单晶X-射线结构分析》、《磁化学基础》等课程教学,参编《无机化学实验》、《无机及分析化学》和《实用仪器分析教程》3部教材。荣获河南大学教学优秀奖和河南大学科研优秀奖。

论文

2016

1. Jun-Wei Zhao,*Yan-Zhou Li, Li-Juan Chen, Guo-Yu Yang*, Research progress on polyoxometalate-based transition-metal–rare-earth heterometallic derived materials: synthetic strategies, structural overview and functional applications,Chem. Commun.2016,52, 4418–4445.

2. Han Xue,Jun-Wei Zhao,*Rui Pan, Bai-Feng Yang, Guo-Yu Yang,* Hong-Sheng Liu*, Diverse ligand-functionalized mixed-valent hexamanganese sandwiched silicotungstates with single-molecule magnet behavior,Chem. Eur. J.2016,22, 12322-12331.

3. Jun-Wei Zhao,*Hai-Lou Li, Xing Ma, Zhigang Xie,* Li-Juan Chen, Yongsheng Zhu*, Lanthanide-connecting and lone-electron-pair active trigonal-pyramidal-AsO3inductive nanosized poly(polyoxotungstate) aggregates and their anticancer activity,Sci. Rep.2016,6, 26406.

4. Hailou Li, Yajie Liu, Rui Zheng, Lijuan Chen,*Jun-Wei Zhao*, Guo-Yu Yang*, Trigonal pyramidal {AsO2(OH)} bridging tetra-nuclear rare-earth encapsulated polyoxotungstate aggregates,Inorg. Chem.2016,55, 3881−3893.

5. Lei-Lei Li, Gao-Juan Cao,Jun-Wei Zhao,*Huan He, Bai-Feng Yang, Guo-Yu Yang*, Lanthanide germanate cluster organic frameworks based on {Ln8Ge12} clusters: from one-dimensional chains to two-dimensional layers and three-dimensional frameworks,Inorg. Chem.2016,55, 5671−5683.

6. Xing Ma, Hailou Li, Lijuan Chen*,Junwei Zhao*, The main progress over the past decade and future outlook on high-nuclear transition-metal substituted polyoxotungstates: from synthetic strategies, structural features to functional properties,Dalton Trans.2016,45, 4935–4960.

7. Jiancai Liu, Jing Yu, Qing Han, Yue Wen, Lijuan Chen* and Junwei Zhao,* First quadruple-glycine bridging mono-lanthanide-substituted borotungstate hybrids,Dalton Trans.2016,45, DOI: 10.1039/C6DT03148J.

8. Lei-Lei Li, Rui Pan,Jun-Wei Zhao,*Bai-Feng Yang, Guo-Yu Yang*, A series of lanthanide germanate cluster organic frameworks,Dalton Trans.2016,45, 11958-11967.

9. Hailou Li, Wen Yang, Xiuhua Wang, Jianru Ma, Lijuan Chen,*Junwei Zhao*, Self-assembly of a family of isopolytungstates induced by the synergistic action of lanthanoids and pH variation in the process of reaction: syntheses, structures and properties,Cryst. Growth Des.2016,16, 108–120.

10. Jiancai Liu, Qing Han, Lijuan Chen,*Junwei Zhao,*A brief review of the crucial progress on heterometallic polyoxotungstates in the past decade,CrystEngComm,2016,18, 842–862.

11. Longhui Sun, Yajie Liu, Xiuhua Wang, Hailou Li, Jie Luo, Lijuan Chen*,Junwei Zhao*,Syntheses, structures and properties of a series of inorganic–organic hybrid copper–lanthanide heterometal comprising germanotungstates with mixed ligands,Synth. Met.2016,217, 256–265.

12.Xiuhua Wang, Qing Han, Lijuan Chen,*Junwei Zhao,*Hydrothermal syntheses, crystal structures and characterization of two new 1-D and 2-D inorganic–organic hybrid polyoxomolybdates[H2dap]2[x-Mo8O26]·2H2O and [Cu(dap)2]2[β-Mo8O26], Inorg. Chem. Commun.2016,63, 24–29.

13. Jiancai Liu, Jing Yu, Qing Han, Bo Shao, Yue Wen, Lijuan Chen,*Junwei Zhao,* Syntheses, structures and properties of four inorganic–organic hybrid heteropolymolybdates functionalized by chiral serine ligands,Inorg. Chem. Commun.2016,70, 136–139.

14.Qing Han, Yue Wen, Jiancai Liu, Lijuan Chen*,Junwei Zhao*, Synthesis, structure and electrochemical properties of an inorganic–organic hybrid CuII-CeIIIheterometallic germanotungstate,Inorg. Chem. Commun.2016,71, 54–60.

15.Peijun Gong, Yanyan Li, Jie Luo, Lijuan Chen,*Junwei Zhao*,Syntheses, structures and properties of two copper-2-picolinic-acid germanomolybdate hybrids with mixed organic components,Inorg. Chem. Commun.2016,71, 113–118.

16. Hailou Li, Shenzhen Chang, XingMa, Jinglin Liu, Jie Luo,*Junwei Zhao,*Two 1-D Krebs-type heteropolyoxotungstates based on [X2W21O72Na(OH)2]13−(X = SbIII, BiIII) units,Inorg. Chem. Commun.2016,72, 45–49.

17. Hailou Li, Yamin Cheng, Jie Luo, Pengtao Ma,Junwei Zhao*Lijuan Chen, Syntheses and structures of two organic-inorganic composite vanadoborates Na2(Hen)4[B18V12O60]·16 H2O and (H2en)6[B18V12O60]2·2tepa·11H2O,Synth. React. Inorg. Met.-Org. Nano-Met. Chem.2016, 46, 687–693.

18.Jie Luo, Kai-fang Song, Hao-zhe Zhao, Jun-wei Zhao,Li-juan Chen,* An organic-inorganic hybrid two-dimensional bilayer assembled from 1:2-type [Er(α-PW11O39)2]11–moieties and [Cu(dap)2]2+linkers,Chinese J. Struct. Chem.2016,35, 39–45.

19.Xuejun Liu, Xing Ma, Jing Zhang, Lijuan Chen *,Junwei Zhao*,Synthesis, structure, and spectroscopic characterization of a 2-D organic–inorganic hybrid CuII–ErIIIheterometallic arsenotungstate,Arabian J. Chem.2016, http://dx.doi.org/10.1016/ j.arabjc.2014.12.002.

2015

1. Xin-Xiong Li, Wei-Hui Fang,Jun-Wei Zhao,*Guo-Yu Yang,* The first 3-connected SrSi2-type 3D chiral framework constructed from {Ni6PW9} building units,Chem. Eur. J.2015,21, 2315–2318.

2. Xiaoqiang Du, Jinli Zhao, Jiaqi Mi, Yong Ding,* Panpan Zhou, Baochun Ma,Junwei Zhao,* Jie Song,* Efficient photocatalytic H2evolution catalyzed by an unprecedented robust molecular semiconductor {Fe11} nanocluster without cocatalysts at neutral conditions,Nano Energy,2015, 16, 247–255.

3.Lijuan Chen, Fang Zhang, Xing Ma, Jie Luo,Junwei Zhao*, Two types of novel tetra-iron substituted sandwich-type arsenotungastates with supporting lanthanide pendants,Dalton Trans.2015, 44, 12598–12612.

4.Lijuan Chen, Jing Cao, Xinghua Li, Xing Ma, Jie Luo,Junwei Zhao*, The First purely inorganic polyoxotungstates constructed from dimeric tungstoantimonate-based iron–rare-earth heterometallic fragments,CrystEngComm,2015, 17, 5002–5013.

5.Xing Ma, Wen Yang, Lijuan Chen*,Junwei Zhao*, Significant developments on rare-earth-containing polyoxometalate chemistry: synthetic strategies, structural diversities and correlative properties,CrystEngComm,2015, 17, 8175-8197.

6. Yingjie Liu, Hailou Li, Jingli Zhang,Junwei Zhao,*Lijuan Chen,* Synthesis, structure, spectroscopic and ferroelectric properties of an acentric polyoxotungstate containing 1:2-type [Sm(α-PW11O39)2]11-fragment and D-proline components,Spectrochim Acta A Mol Biomol Spectrosc.2015, 134, 101–108.

7. Jiancai Liu, Yudong Zhang, Sensen Shang, Yanzhou Li, Lijuan Chen,*Junwei Zhao*,Syntheses, structures and properties of three metal-organic complexes containing 2,2'-dipyridyl-5,5'-dicarboxylate ligands,J. Solid State Chem.2015,221, 5-13.

8. Jie Luo, Xing Ma, Lijuan Chen,*Junwei Zhao,*Synthesis, structure and properties of an organic–inorganic hybrid independent 1-D double-chain Keggin-type silicotungstate with mixed ligands,Inorg. Chem. Commun.2015,54, 25–30.

9. Hailou Li, Wen Yang, Yun Chai, Lijuan Chen,Junwei Zhao,* A novel Dawson-like cerium(IV)-hybridizing selenotungstate Na13H7[Ce(SeW17O59)2]·31H2O,Inorg. Chem. Commun.2015,56, 35–40.

10.Xing Ma, Kaifang Song, Jing Cao, Peijun Gong, Hailou Li, Lijuan Chen*,Junwei Zhao*, Synthesis, structure and electrochemical properties of a FeIII–CeIIIheterometallic sandwich-type tungstoantimonate with novel 2-D infinite structure [Ce(H2O)8][Ce(H2O)6][Fe4(H2O)10(B-β-SbW9O33)2]·16H2O,Inorg. Chem. Commun.2015,60, 65–70.

11.Wen Yang, Hailou Li, Yanyan Li, Lijuan Chen*,Junwei Zhao*,Syntheses, structures and properties of a series of 3s–5d–4f mixed metal substituted sandwich-type arsenotungstates,Inorg. Chem. Commun.2015,60, 71–76.

12. Hailou Li, Bo Shao, Yanyan Li, Lijuan Chen,*Junwei Zhao,*Two octamolybdate-based hybrids functionalized by 1,3-bis[tris(hydroxymethyl)methylamino]propane ligand,Inorg. Chem. Commun.2015,61, 68–72.

13.Jie Luo, Jian-Cai Liu, Bo Shao, Li-Juan Chen,*Jun-Wei Zhao,*Two organic–inorganic hybrids assembled from transition–metal complexes and Keggin-type silicotungstates,J. Clust. Sci.2015,26, 2005-2022.

14. Jie Luo, Pengfei Cheng,Junwei Zhao,*Lijuanchen, Synthesis, crystal structure, and magnetic property of an organic–inorganic hybrid silicotungstate with supporting dinuclear copper complexes,Synth. React. Inorg. Met.-Org. Nano- Met. Chem.2015,45, 682–687.

2014

1. Ling Huang, Sa-Sa Wang,Jun-Wei Zhao,* Lin Cheng, Guo-Yu Yang*, Synergistic Combination of Multi-ZrIVCations and Lacunary Keggin Germanotungstates Leading to a Gigantic Zr24-Cluster-Substituted Polyoxometalate, J. Am. Chem. Soc.2014, 136, 7637−7642.

2. Jian Zhou,Jun-Wei Zhao, Qi Wei, Jie Zhang, Guo-Yu Yang*, Two Tetra-CdII-Substituted Vanadogermanate Frameworks,J. Am. Chem. Soc.2014, 136, 5065−5071.

3. Xin-Xiong Li, Wei-Hui Fang,Jun-Wei Zhao,*Guo-Yu Yang,* Hydrothermal combination of trilacunary Dawson phosphotungstates and hexanickel clusters: from an isolated cluster to a 3D framework,Chem. Eur. J.2014,20, 17324–17332.

4. Yanzhou Li, Jie Luo, Lijuan Chen,*Junwei Zhao*, Recent progress in metal functionalized germanotungstates: from structures to properties,RSC Adv.2014,4, 50679–50692.

5. Jun-Wei Zhao,*, Jing-Li Zhang, Yan-Zhou Li, Jing Cao, Li-Juan Chen*, Novel one-dimensional organic−inorganic polyoxometalate hybrids constructed from heteropolymolybdate units and copper−aminoacid complexes,Cryst. Growth Des.2014,14, 1467−1475.

6. Jun-Wei Zhao,* Yan-Zhou Li, Fan Ji, Jing Yuan, Li-Juan Chen, Guo-Yu Yang,* Syntheses, structures and electrochemical properties of a class of 1-D double chain polyoxotungstate hybrids [H2dap][Cu(dap)2]0.5[Cu(dap)2(H2O)][Ln(H2O)3(α-GeW11O39)]·3H2O,Dalton Trans.2014,43, 5694–5706.

7. Junwei Zhao,*Jing Cao, Yanzhou Li, Jing Zhang, Lijuan Chen,* First tungstoantimonate-based transition-metal–lanthanide heterometallic hybrids functionalized by aminoacid ligands,Cryst. Growth Des.2014,14, 6217-6229.

8.Junwei Zhao,*Hailou Li, Yanzhou Li, Chunyang Li, Zhenling Wang, Lijuan Chen,* Rectangle versus square oxalate-connective tetra-lanthanide cluster anchored in lacunary Lindqvist isopolytungstates: syntheses, structures and properties,Cryst. Growth Des.2014,14, 5495−5505.

9.Xuejun Liu, Hailou Li, Jie Luo, Xing Ma,Junwei Zhao,*Hydrothermal syntheses, structures and properties of two 3-D organic–inorganic hybrid mixed-valent polyoxovanadates [Ni(en)2][VIV4VV2O14] and [Cu(en)2][VIV2VV3O12.5],Synthetic Metals2014,198, 267–273.

10.Yingjie Liu, Jing Cao, Yujie Wang, Yanzhou Li,Junwei Zhao,*Lijuan Chen,* Pengtao Ma, Jingyang Niu, Hydrothermal synthesis and structural characterization of an organic–inorganic hybrid sandwich-type tungstoantimonate [Cu(en)2(H2O)]4[Cu(en)2(H2O)2][Cu2Na4(α-SbW9O33)2]·6H2O,J. Solid State Chem.2014,209, 113–119.

11.Jie Luo, Hailou Li, Xinxin Chen, Jianru Ma, Lijuan Chen,Junwei Zhao,*A 3-D framework based on mono-copperIIsubstituted silicotungstate units [Cu(dap)2(H2O)]2[Cu(dap)2][α-SiW11CuO39]·2H2O,Inorg. Chem. Commun.2014,50, 19–23.

12.Yuanqing Xu, Yanzhou Li, Junwei Zhao,* Dongying Shi, Lijuan Chen, Hydrothermal synthesis and structural characterization of a 1-D inorganic-organic composite tetra-nickel substituted sandwich-type phosphotungstate,Synth. React. Inorg. Met.-Org. Nano- Met. Chem.2014,44, 118–124.

13.Jingli Zhang, Xiqing Yan, Dongying Shi,Junwei Zhao,*Lijuan Chen, Synthesis, structure, and properties of a 2-D organic–inorganic hybrid phosphotungstate-based CuII–LaIIIheterometallic derivative,Synth. React. Inorg. Met.-Org. Nano-Met. Chem.2014,44, 171–176.

14.Yan-Ying Li,Jun-Wei Zhao,* Qi Wei, Bai-Feng Yang,Huan He, Guo-Yu Yang*, Two organic–inorganic Hybrid 3D {P5W30}-based heteropolyoxotungstates with transition-metal/Ln–carboxylate–Ln connectors,Chem. Asian J.2014, 9, 858–867.

15. Lin Cheng,Jun-Wei Zhao, Guo-Yu Yang*, Two Cu-complex directed aluminoborates: from 2D layer to 3D framework,DaltonTrans.2014,43, 7324-7330.

16. Jun Wang,Jun-Wei Zhao,* Hai-Yan Zhao, Bai-Feng Yang, Huan He, Guo-Yu Yang, Syntheses, structures and properties of two multi-iron–samarium/multi-iron substituted germanotungstates,CrystEngComm,2014, 16, 252–259.

17.Hai-Yan Zhao, Jun-Wei Zhao,* Bai-Feng Yang, Huan He, Guo-Yu Yang*, A series of organic–inorganic hybrids based on lanthanide-substituted Dawson-type phosphotungstate dimers and copper–en linkers,CrystEngComm,2014,16, 2230–2238.

18. Rui-Qin Li, Yan-Ying Li, Bai-Feng Yang, Huan He,Jun-Wei Zhao,*Guo-Yu Yang*, The first 2-D organic–inorganic hybrid containing two types of hexa-CuIIsandwiched polyoxotungstate units and mixed amines,Inorg. Chem. Commun.2014, 44, 191–194.

19. Bin Cai,Jun-Wei Zhao*,Bai-Feng Yang, Huan He, Guo-Yu Yang*, Two hexa-Ni-substituted AsW9O34clusters functionalized by organic ligands,J. Clust. Sci.2014,25, 1047–1059.

20. Yan-Ying Li,Jun-Wei Zhao,*Bai-Feng Yang, Huan He, Guo-Yu Yang*, Hydrothermal syntheses and structural characterization of two 3-D supramolecular networks constructed from tetra-CoIIsandwiched polyoxometalates,J. Clust. Sci.2014,25, 949–957.

21. Bin Cai,Jun-Wei Zhao*,Bai-Feng Yang, Huan He, Guo-Yu Yang*, Temperature-dependent organic functionalization of {Ni6PW9} species: from isolated clusters to 1D chain,J. Clust. Sci.2014,25, 1069–1084.

22. Yan-Ying Li,Jun-Wei Zhao,*Wei Qi, Bai-Feng Yang, Guo-Yu Yang*, A 3D polyoxometalate network based on the tetra-CoIIsandwiched phosphotungstate units linked by Cs+cations,J. Clust. Sci.2014,25, 549–557.

23. Hai-Yan Zhao,Jun-Wei Zhao,*Bai-Feng Yang, Wei Qi, Guo-Yu Yang*, Two organic-inorganic hybrids assembled by carboxylate-bridging lanthanide-substituted polyoxometalate dimers with copper-ethylendiamine cations,J. Clust. Sci.2014,25, 667–680.

24.Yan-Ying Li,Jun-Wei Zhao,*Wei Qi, Bai-Feng Yang, Guo-Yu Yang*, Synthesis and characterization of a 1D chain-like Cu-6 substituted sandwich-type phosphotungstate with pendant dinuclear Cu-azido complexes,J. Solid State Chem.2014,210,166–170.

25.Qin Meng, Huan He, Bai-Feng Yang,Jun-Wei Zhao,*Guo-Yu Yang,* Synthesis and characterization of a 3-D framework constructed from [V12B18O54(OH)6(H2O)]10-clusters and K+cations,J. Clust. Sci.2014,25, 1273–1282.

26.Bin Cai, Bai-Feng Yang, Huan He,Jun-Wei Zhao,*Guo-Yu Yang,* Amino acid functionalization of {Ni6PW9}-based clusters under hydrothermal conditions,J. Clust. Sci.2014,25, 1283–1293.

27. Ying-Bing Lu, Fang-Mei Jian, Shuang Jin,Jun-Wei Zhao,*Yong-Rong Xie, Guo-Tian Luo, Three-dimensional extended frameworks constructed from dinuclear lanthanide(III) 1,4-naphthalenedicarboxylate units with bis(2,2'-biimidazole) templates: syntheses, structures, and magnetic and luminescent properties,Cryst. Growth Des.2014, 14, 1684−1694.

著作:

1. 《无机化学实验》, ISBN 978-7-122-08934-2,化学工业出版社,2010年8月,参编约6万字。

2. 《无机及分析化学》,ISBN 978-7-308-09015-3,浙江大学出版社,2011年9月,参编约7万字。

3. 《实用仪器分析教程》, ISBN 978-7-308-12144-6, 浙江大学出版社,2013年9月,参编约8.1万字。

项目:

1. 多核稀土取代含As, Sb, Bi, Se, Te杂原子多钨氧酸盐纳米簇的设计合成及抗癌活性研究(21571048), 国家自然科学基金,主持,2016.1–2019.12。

2. 高核稀土取代多钨氧酸盐纳米簇合物的设计、制备及抗癌活性研究(16HASTIT001), 河南省高校科技创新人才支持计划, 主持,2016.1–2018.12。

3. 多核稀土取代多钨氧酸盐纳米簇的设计合成及抗癌活性研究(20160016), 结构化学国家重点实验室科学基金, 主持,2016.1–2018.12。

4. 含孤对电子杂原子的多钨氧酸盐3d-4f异金属磁性材料的设计合成和性能研究(142300410451),河南省基础与前沿技术研究计划项目, 5万,主持,2014.1-2016.12。

4. 有机-无机杂化钨氧簇基材料的制备、铁电及磁性研究(21101055),国家自然科学基金,主持,2012.1–2014.12。

5. 有机-无机杂化多钨氧酸盐基3d-4f异金属衍生材料的制备、铁电及磁性研究(201104392),中国博士后特别资助,主持,2011.10–2013.1。

6. 无机-有机杂化钨-氧簇基铁电和磁性材料的制备与性能研究(20120013),结构化学国家重点实验室开放基金,主持,2012.1–2014.12。

7. 多金属氧酸盐基3d-4f金属衍生物的合成及荧光磁性研究(20100470996),中国博士后科学基金,主持,2010.8–2013.1。

8. 稀土簇与缺位多金属氧酸盐簇的组装化学及相关性能研究(092300410119),河南省科技厅自然科学基金,主持,2009.1–2011.12。

9. 有机-无机杂化的过渡金属取代多钨氧酸盐的制备和磁性研究(2010B150006),河南省教育厅自然科学基金,主持,2010.05–2012.12。

10. 杂多钨氧酸盐基有机-无机杂化压电材料的制备及相关性能研究(XXJC20140001),河南大学新兴交叉及特色学科培育计划,主持,2014.05–2018.05。

11. 稀土簇与缺位多金属氧酸盐簇的组装化学及相关性能研究(2008YBZR010), 河南大学自然科学基金,主持,2009.1–2010.12。

12. 多金属氧酸盐基的稀土簇荧光材料研究, 2009年河南大学大学生创新性实验计划项目,指导,2009.6–2011.5。

13. 多金属氧酸盐基3d-4f异金属衍生物的合成及荧光磁性研究, 2012年河南大学大学生创新性实验计划项目,指导,2012.6–2014.5。

14. 杂化钨氧簇基材料的制备、铁电及磁性研究,2013年河南大学大学生创新性实验计划项目,指导,2013.6–2015.5。

15. 砷/锑杂原子多钨氧酸盐过渡-稀土异金属磁性材料的设计合成和性能研究,2014年河南大学大学生创新性实验计划项目,指导,2014.6–2016.5。

16. 杂多钼氧酸盐3d-4f异金属衍生材料的设计合成及其对有机染料光降解性能研究, 2013年河南大学大学生创新性实验计划项目,指导,2015.6–2017.5。

获奖成果:

1. Combination between lacunary polyoxometalates and high-nuclear transition metal clusters under hydrothermal conditions: first (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu8} cluster,河南省第十届自然科学优秀学术论文一等奖,排名第一,2010年4月。

2. Two-dimensional extended (4,4)-topological network constructed from tetra-NiII-substituted sandwich-type Keggin polyoxometalate building blocks and NiII-organic cation bridges,河南省第十届自然科学优秀学术论文一等奖,排名第一,2010年4月。

3. Hydrothermal syntheses, crystal structures and properties of 0-D, 1-D and 2-D organic–inorganic hybrid borotungstates constructed from Keggin-type heteropolyanion [α-BW12O40]5-,河南省首届自然科学学术奖—河南省自然科学优秀学术论文二等奖,排名第一,2011年9月。

4.A combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. Part II: From double cluster, dimer, and tetramer to three-dimensional frameworks,河南省教育厅优秀科技论文一等奖,排名第一,2010年6月。

5. Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions: first 65·8 CdSO4-type 3-D framework built by hexa-CuIIsandwiched polyoxotungstates,河南省教育厅优秀科技论文一等奖,排名第一,2012年6月。

6. Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of [{FeIIFeIII123-OH)124-PO4)4} (B-α-PW9O34)4]22-, 河南省教育厅优秀科技论文一等奖,排名第一,2012年6月。

7. 杂多阴离子稀土衍生物的合成、结构分析及性质,河南省教育厅科技成果一等奖、排名第四、2011年6月。

8. Novel polyoxometalate hybrids containing copper-lanthanide heterometallic germanotungstate / lanthanide-germanotungstate fragments,河南省第二届自然科学学术奖—河南省自然科学优秀学术论文二等奖,排名第一,2013年12月。

9. Two 1-D multi-nickel substituted arsenotungstate aggregates,河南省第二届自然科学学术奖—河南省自然科学优秀学术论文二等奖,排名第一,2013年12月。

10. Two organic–inorganic hybrid 1-D and 3-D polyoxotungstates constructed from hexa-CuII substituted sandwich-type arsenotungstate units,河南省第二届自然科学学术奖—河南省自然科学优秀学术论文三等奖,排名第一,2013年12月。

11. 赵俊伟, 史东英, 陈利娟,马鹏涛,王敬平, Tetrahedral Polyoxometalate Nanoclusters withTetrameric Rare-Earth Cores and Germanotungstate Vertexes, 河南省第三届自然科学学术奖—河南省自然科学优秀学术论文二等奖,河南省人力资源和社会保障厅和河南省科学技术协会,2015年。

12. 赵俊伟,李海楼,李彦舟,李春阳,王珍玲,Rectangle versus SquareOxalate-Connective Tetralanthanide Cluster Anchored in Lacunary LindqvistIsopolytungstates: Syntheses, Structures, and Properties,河南省第三届自然科学学术奖—河南省自然科学优秀学术论文三等奖,河南省人力资源和社会保障厅和河南省科学技术协会,2015年。

13.有机-无机杂化过渡-稀土异金属取代锗钨酸盐晶态储氢材料及其制备方法,专利号:ZL 2012 1 0423422.0, 中国专利局授予的发明专利, 授权时间:2014年4月,排名:第一。

14. 二(2-乙酰吡嗪基)硫代缩二氨基脲及其铋(III)配合物的制备方法及应用,专利号:ZL 2012 1 0493229.4, 中国专利局授予的发明专利, 授权时间:2014年9月,排名:第一。

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