Name: Heng-Ying Xiong

Henan University “Huanghe” Scholar

Department: College of Chemistry and Chemical Engineering, Henan University

Email: xionghengying@vip.henu.edu.cn, xionghengying@163.com

：

10/2013–03/2017, Ph.D. student in Organic Chemistry, INSA-Rouen, UMR 6014-COBRA

09/2010–07/2013, Master student in Organic Chemistry, Tianjin University

09/2006–07/2010, Undergraduate student in Chemistry, Neijiang Normal University

Research Experience:

03/2018–present, College of Chemistry and Chemical Engineering, Henan University, “Huanghe Scholar”

Research Interests

Activation of inert bond

Synthesis and application of functional molecules

Funding:

Henan University Huanghe Scholar Starting Grant (2018-2022)

：

1. H.-Y. Xiong, A. Bayle, X. Pannecoucke, T. Besset, “An Electrophilic Reagent for the Direct Introduction of the SCF2PO(OEt)2 Group to Molecules”.

Angew. Chem. Int. Ed. 2016, 55, 13490.

2. H.-Y. Xiong, X. Pannecoucke, T. Besset. “Recent Advances in the Synthesis of SCF2H- and SCF2FG Containing Molecules”.

Chem. Eur. J. 2016, 22, 16734.

3. H.-Y. Xiong, X. Pannecoucke, T. Besset. “Oxidative trifluoromethylthiolation and thiocyanation of amines: a general approach to N–S bond formation”.

Org. Chem. Front. 2016, 3, 620.  

4. H.-Y. Xiong, D. Cahard, X. Pannecoucke, T. Besset. “Pd-Catalyzed Directed Chlorination of Unactivated C(sp3)–H Bonds at Room Temperature”.

Eur. J. Org. Chem. 2016, 3625. (Hottest articles in New Synthetic Methods, Wiley).

5. H.-Y. Xiong, T. Besset, D. Cahard, X. Pannecoucke. “Palladium(II)-Catalyzed Directed Trifluoromethylthiolation of Unactivated C(sp3)–H Bonds”.

J. Org. Chem. 2015, 80, 4204.

6. H.-Y. Xiong, Z.-Y. Yang, Z. Chen, J.-L. Zeng, J. Nie, J.-A. Ma. “Copper-Catalyzed One-Pot Denitrogenative-Dehydrogenative-Decarboxylative Coupling of β-Ketoacids with Trifluorodiazoethane: Facile Access to Trifluoromethylated Aldol Products”.

Chem. Eur. J. 2014, 20, 8325.

7. M.-C. Belhomme, D. Dru, H.-Y. Xiong, D. Cahard, T. Besset, T. Poisson, X. Pannecoucke. “Copper Mediated Direct Functionalization of Unsaturated C–C Bonds using BrCF2CO2Et: a Straightforward Access to Highly Valuable Difluoromethylated Alkenes”.

Synthesis 2014, 46, 1859.

8. W.-T. Meng, Y. Zheng, J. Nie, H.-Y. Xiong, J.-A. Ma. “Organocatalytic Asymmetric One-Pot Sequential Conjugate Addition/Dearomative Fluorination: Synthesis of Chiral Fluorinated Isoxazol-5(4H)-ones”.

J. Org. Chem. 2013, 78, 559.

9. Y. Zheng, H.-Y. Xiong, M.-Q. Hua, J.-A. Ma. “Biomimetic catalytic enantioselective decarboxylative aldol reaction of β-ketoacids with trifluoromethyl ketones”.

Chem. Commun. 2012, 48, 4308.

10. X.-J. Li, H.-Y. Xiong, M.-Q. Hua, J. Nie, Y. Zheng, J.-A. Ma. “Convenient and efficient decarboxylative aldol reaction of malonic acid half esters with trifluoromethyl ketones”. Tetrahedron Lett. 2012, 53, 2117.

11. J. Nie, M.-Q. Hua, H.-Y. Xiong, Y. Zheng, J.-A. Ma. “Asymmetric phase-transfer-catalyzed conjugate addition of glycine imine to exocyclic α,β-unsaturated ketones construction of polycyclic imines containing three stereocenters”.

J. Org. Chem. 2012, 77, 420.