化学系

赵俊伟

发布时间:2017-10-23
浏览次数:
来源: 管理员

http://hdcms.henu.edu.cn/_vsl/65C143FE1681229E56F6AB858D0888C0/DD53728F/1BBC?e=.jpg

 

姓名:赵俊伟(博士)

系别:化学系

职称:河南省特聘教授,博士生导师

电话:0371-23881589

传真:0371-23881589

邮箱:zhaojunwei@henu.edu.cn

个人简介:河南大学师德标兵,河南大学第五届校学术委员会委员,河南省优秀教师,河南省高等学校优秀共产党员,河南省高等学校青年骨干教师,河南省高校科技创新人才,河南省科技创新人才杰出青年基金获得者,宝钢教育奖,中国青少年科技创新奖获得者,教育部学位中心学位论文通讯评议专家,国家自然科学基金委通讯评审专家,河北、浙江、福建、安徽等省自然科学基金通讯评议专家,《American Journal of Chemistry and Application》和《Jacobs Journal of Inorganic Chemistry》的编辑部成员。

主要教育经历:

  1998.9-2002.7  河南大学   化学      本科

  2002.9-2005.7  河南大学   无机化学  硕士

  2005.9-2008.7  中国科学院福建物质结构研究所   无机化学  博士

  2010.1-2012.6  河南大学化学博士后流动站       无机化学  博士后

主要学术经历:

  2008.07-2010.10   河南大学化学化工学院  讲师

  2010.10-2014.11   河南大学化学化工学院  副教授

  2014.11-至今      河南大学化学化工学院  教授

  2016.03-2018.09   河南大学化学化工学院  河南大学特聘教授

  2018.09-至今      河南大学化学化工学院  河南省特聘教授

  2012.07           河南省高等学校青年骨干教师

  2015.06           河南省教育厅学术技术带头人

  2015.11           河南省高校科技创新人才获得者

  2016.01           河南省科技创新人才杰出青年基金获得者

  2018.08           河南省优秀教师

研究领域:

研究方向:

(1) 新型多金属氧酸盐功能材料的合成与制备化学和其发光、电学、磁性、电化学识别等物理化学性能研究

(2) 孤对电子空间效应诱导的簇合物的设计合成、溶液化学行为、质子导电及细胞药物活性的研究

相关研究成果在J. Am. Chem. Soc., Angew. Chem. Int. Ed., Nano Enery, Chem. Commun., Chem. Eur. J., Chem. Asian J.; Inorg. Chem., Cryst. Growth Des., Dalton Trans.等国外知名杂志上发表学术论文110余篇。主持国家自然科学基金3项、河南省科技创新人才杰出青年基金1项、河南省高校科技创新人才支持计划1项和河南省科技厅、河南省教育厅自然科学基金及其它项目等共计10余项,获批国家发明专利4项。荣获河南省科技进步二等奖1项(排名第四)、河南省教育厅科技成果一等奖1项、河南省自然科学优秀论文奖一等奖3项、二等奖4项、河南省教育厅优秀科技论文一等奖2项。

讲授课程:

  主要担任本科生《无机化学》、《化学理论知识应用与科研实践》、《无机化学实验》、《无机及分析化学实验》和研究生《单晶X-射线结构分析》、《磁化学基础》等课程教学,参编《无机化学实验》、《无机及分析化学》和《实用仪器分析教程》3部教材。荣获河南大学教学优秀奖和河南大学科研优秀奖。

主要成果:

论文

1.       Jian-Cai Liu, Qing Han, Li-Juan Chen, Jun-Wei Zhao,* Carsten Streb,* Yu-Fei Song*, Aggregation of Giant Cerium-Bismuth Tungstate Clusters into a 3D Porous Framework with High Proton Conductivity, Angew. Chem. Int. Ed. 2018, 57, 8416–8420.

2.       Ling Huang, Sa-Sa Wang, Jun-Wei Zhao,* Lin Cheng, Guo-Yu Yang*, Synergistic combination of multi-ZrIV cations and lacunary Keggin germanotungstates leading to a gigantic Zr24-cluster-substituted polyoxometalate, J. Am. Chem. Soc. 2014, 136, 7637−7642.

3.       Jian Zhou, Jun-Wei Zhao, Qi Wei, Jie Zhang, Guo-Yu Yang,* Two Tetra-CdII-Substituted Vanadogermanate Frameworks, J. Am. Chem. Soc. 2014, 136, 5065−5071.

4.       Xiaoqiang Du, Jinli Zhao, Jiaqi Mi, Yong Ding,* Panpan Zhou, Baochun Ma, Junwei Zhao,* Jie Song,* Efficient photocatalytic H2 evolution catalyzed by an unprecedented robust molecular semiconductor {Fe11} nanocluster without cocatalysts at neutral conditions, Nano Energy, 2015, 16, 247–255.

5.       Jun-Wei Zhao,* Yan-Zhou Li, Li-Juan Chen, Guo-Yu Yang*, Research progress on polyoxometalate-based transition-metal–rare-earth heterometallic derived materials: synthetic strategies, structural overview and functional applications, Chem. Commun. 2016, 52, 4418–4445.

6.       Hai-Lou Li, Ya-Jie Liu, Jing-Lin Liu, Li-Juan Chen, Jun-Wei Zhao,* Guo-Yu Yang,* Structural transformation from dimerization to tetramerization of serine-decorated rare-earth incorporated arsenotungstates induced by the usage of rare-earth salts, Chem. Eur. J. 2017, 23, 2673–2689.

7.       Han Xue, Jun-Wei Zhao,* Rui Pan, Bai-Feng Yang, Guo-Yu Yang,* Hong-Sheng Liu*, Diverse ligand-functionalized mixed-valent hexamanganese sandwiched silicotungstates with single-molecule magnet behavior, Chem. Eur. J. 2016, 22, 12322-12331.

8.       Xin-Xiong Li, Wei-Hui Fang, Jun-Wei Zhao,* Guo-Yu Yang,* The first 3-connected SrSi2-type 3D chiral framework constructed from {Ni6PW9} building units, Chem. Eur. J. 2015, 21, 2315–2318.

9.       Xin-Xiong Li, Wei-Hui Fang, Jun-Wei Zhao,* Guo-Yu Yang,* Hydrothermal combination of trilacunary Dawson phosphotungstates and hexanickel clusters: from an isolated cluster to a 3D framework, Chem. Eur. J. 2014, 20, 17324–17332.

10.   Jing-Lin Liu, Meng-Tian Jin, Li-Juan Chen,* Jun-Wei Zhao*, First dimethyltin-functionalized rare-earth incorporated tellurotungstates consisting of {B-α-TeW7O28} and {W5O18} mixed building units, Inorg. Chem. 2018, 57, 12509–12520.

11.   Yanhong Chen, Longhui Sun, Shenzhen Chang, Lijuan Chen,* Junwei Zhao*, Lanthanide nature and various coordination mode of 2-picolinic acid ligand tuning three types of rare 3d−4f heterometallic tungstoantimonates, Inorg. Chem. 2018, http://dx.doi.org/10.1021/acs.inorgchem.8b02103.

12.   Qing Han, Jian-Cai Liu, Yue Wen, Li-Juan Chen,* Jun-Wei Zhao,* Guo-Yu Yang*, Tellurotungstate-based organotin−rare-earth heterometallic hybrids with four organic components, Inorg. Chem. 2017, 56, 7257–7269.

13.   Qing Han, Yue Wen, Jian-Cai Liu, Wu Zhang, Li-Juan Chen,* Jun-Wei Zhao,* Rare-Earth-Incorporated Tellurotungstate Hybrids Functionalized by 2-Picolinic Acid Ligands: Syntheses, Structures, and Properties, Inorg. Chem. 2017, 56, 13228−13240.

14.   Hailou Li, Yajie Liu, Rui Zheng, Lijuan Chen,* Jun-Wei Zhao,* Guo-Yu Yang*, Trigonal pyramidal {AsO2(OH)} bridging tetra-nuclear rare-earth encapsulated polyoxotungstate aggregates, Inorg. Chem. 2016, 55, 3881−3893.

15.   Lei-Lei Li, Gao-Juan Cao, Jun-Wei Zhao,* Huan He, Bai-Feng Yang, Guo-Yu Yang*, Lanthanide germanate cluster organic frameworks based on {Ln8Ge12} clusters: from one-dimensional chains to two-dimensional layers and three-dimensional frameworks, Inorg. Chem. 2016, 55, 5671−5683.

16.   Jiancai Liu, Jie Luo, Qing Han, Jing Cao, Lijuan Chen,* You Song,* Junwei Zhao,* Coexistence of long-range ferromagnetic ordering and spin-glass behavior observed in the first inorganic–organic hybrid 1-D oxalate-bridging nona-MnII sandwiched tungstoantimonate chain, J. Mater. Chem. C, 2017, 5, 2043–2055. (From themed collection 2017 Journal of Materials Chemistry C HOT Papers)

17.   Hai-Lou Li, Ya-Jie Liu, Ya-Min Li, Li-Juan Chen,* Jun-Wei Zhao,* Guo-Yu Yang*, Unprecedented Selenium and Lanthanide Simultaneously Bridging Selenotungstate Aggregates Stabilized by Four Tetra-vacant Dawson-like {Se2W14} Units, Chem. Asian J. 2018, 13, 2897–2907.

18.   Pei-Jun Gong, Jing-Jing Pang, Hui-Fen Hu, Hui-Jie Li, Li-Juan Chen,* Jun-Wei Zhao*, Ligand-Controlled Assembly of Heteropolyoxomolybdates Constructed from Plenary Keggin Germanomolybdates and Cu-Ln Heterometallic Units, Chem. Asian J. 2018, DOI: 10.1002/asia.201801255.

19.   Yan-Ying Li, Jun-Wei Zhao,* Qi Wei, Bai-Feng Yang,Huan He, Guo-Yu Yang*, Two organic–inorganic Hybrid 3D {P5W30}-based heteropolyoxotungstates with transition- metal/Ln–carboxylate–Ln connectors, Chem. Asian J. 2014, 9, 858–867.

20.   Jun-Wei Zhao,* Hai-Lou Li, Xing Ma, Zhigang Xie,* Li-Juan Chen, Yongsheng Zhu*, Lanthanide-connecting and lone-electron-pair active trigonal-pyramidal-AsO3 inductive nanosized poly(polyoxotungstate) aggregates and their anticancer activity, Sci. Rep. 2016, 6, 26406.

21.   Ya-Jie Liu, Meng-Tian Jin, Li-Juan Chen*, Jun-Wei Zhao*, Recent advances in isopolyoxotungstates and their derivatives, Acta Cryst. 2018, C74, 1202–1221.

22.   Xing Ma, Hailou Li, Lijuan Chen*, Junwei Zhao*, The main progress over the past decade and future outlook on high-nuclear transition-metal substituted polyoxotungstates: from synthetic strategies, structural features to functional properties, Dalton Trans. 2016, 45, 4935–4960.

23.   Lei-Lei Li, Rui Pan, Jun-Wei Zhao,* Bai-Feng Yang, Guo-Yu Yang*, A series of lanthanide germanate cluster organic frameworks, Dalton Trans. 2016, 45, 11958-11967.

24.   Jiancai Liu, Jing Yu, Qing Han, Yue Wen, Lijuan Chen,* Junwei Zhao,* First quadruple-glycine bridging mono-lanthanide-substituted borotungstate hybrids, Dalton Trans. 2016, 45, 16471–16484.

25.   Lijuan Chen, Fang Zhang, Xing Ma, Jie Luo, Junwei Zhao*, Two types of novel tetra-iron substituted sandwich-type arsenotungastates with supporting lanthanide pendants, Dalton Trans. 2015, 44, 12598–12612.

26.   Jun-Wei Zhao,* Yan-Zhou Li, Fan Ji, Jing Yuan, Li-Juan Chen, Guo-Yu Yang,* Syntheses, structures and electrochemical properties of a class of 1-D double chain polyoxotungstate hybrids [H2dap][Cu(dap)2]0.5[Cu(dap)2(H2O)][Ln(H2O)3(α- GeW11O39)]·3H2O, Dalton Trans. 2014, 43, 5694–5706.

27.   Yajie Liu, Hailou Li, Changtong Lu, Peijun Gong, Xiaoyun Ma, Lijuan Chen,* Junwei Zhao*, Organocounterions-assisted and pH-controlled self-assembly of five nanoscale high-nuclear lanthanide substituted heteropolytungstates, Cryst. Growth Des. 2017, 17, 3917−3928.

28.   Xiuhua Wang, Yajie Liu, Mengtian Jin, Yuxing Wu, Lijuan Chen,* Jun-Wei Zhao*, Two families of rare-earth-substituted Dawson-type monomeric and dimeric phosphotungstates functionalized by carboxylic ligands, Cryst. Growth Des. 2017, 17, 5295–530.

29.   Hailou Li, Wen Yang, Xiuhua Wang, Jianru Ma, Lijuan Chen,* Junwei Zhao*, Self-assembly of a family of isopolytungstates induced by the synergistic action of lanthanoids and pH variation in the process of reaction: syntheses, structures and properties, Cryst. Growth Des. 2016, 16, 108–120.

30.   Jun-Wei Zhao,*, Jing-Li Zhang, Yan-Zhou Li, Jing Cao, Li-Juan Chen*, Novel one-dimensional organic−inorganic polyoxometalate hybrids constructed from heteropolymolybdate units and copper−aminoacid complexes, Cryst. Growth Des. 2014, 14, 1467−1475.

31.   Jun-Wei Zhao,* Jing Cao, Yan-Zhou Li, Jing Zhang, Li-Juan Chen,* First tungstoantimonate-based transition-metal–lanthanide heterometallic hybrids functionalized by aminoacid ligands, Cryst. Growth Des. 2014, 14, 6217-6229.

32.   Junwei Zhao,* Hailou Li, Yanzhou Li, Chunyang Li, Zhenling Wang, Lijuan Chen,* Rectangle versus square oxalate-connective tetra-lanthanide cluster anchored in lacunary Lindqvist isopolytungstates: syntheses, structures and properties, Cryst. Growth Des. 2014, 14, 5495−5505.

33.   Ying-Bing Lu, Fang-Mei Jian, Shuang Jin, Jun-Wei Zhao,* Yong-Rong Xie, Guo-Tian Luo, Three-dimensional extended frameworks constructed from dinuclear lanthanide(III) 1,4-naphthalenedicarboxylate units with bis(2,2'-biimidazole) templates: syntheses, structures, and magnetic and luminescent properties, Cryst. Growth Des. 2014, 14, 1684−1694.

34.   Junwei Zhao,* Dongying Shi, Lijuan Chen,* Pengtao Ma, Jingping Wang, Jian Zhang,* Jingyang Niu,* Tetrahedral polyoxometalate nanoclusters with tetrameric rare-earth cores and germanotungstate vertexes, Cryst. Growth Des. 2013, 13, 4368−4377.

35.   Peijun Gong, Yanyan Li, Cuiping Zhai, Jie Luo, Xuemeng Tian, Lijuan Chen*, Junwei Zhao,* Syntheses, structural characterization and photophysical properties of two series of rare-earth-isonicotinic-acid containing Waugh-type manganomolybdates, CrystEngComm, 2017, 19, 834–852.

36.   Jiancai Liu, Qing Han, Lijuan Chen,* Junwei Zhao,* A brief review of the crucial progress on heterometallic polyoxotungstates in the past decade, CrystEngComm, 2016, 18, 842–862.

37.   Lijuan Chen, Jing Cao, Xinghua Li, Xing Ma, Jie Luo, Junwei Zhao*, The First purely inorganic polyoxotungstates constructed from dimeric tungstoantimonate-based iron–rare-earth heterometallic fragments, CrystEngComm, 2015, 17, 5002–5013.

38.   Xing Ma, Wen Yang, Lijuan Chen*, Junwei Zhao*, Significant developments on rare-earth-containing polyoxometalate chemistry: synthetic strategies, structural diversities and correlative properties, CrystEngComm, 2015, 17, 8175-8197.

39.   Jun Wang, Jun-Wei Zhao,* Hai-Yan Zhao, Bai-Feng Yang, Huan He, Guo-Yu Yang, Syntheses, structures and properties of two multi-iron–samarium/multi-iron substituted germanotungstates, CrystEngComm, 2014, 16, 252–259.

40.   Hai-Yan Zhao, Jun-Wei Zhao,* Bai-Feng Yang, Huan He, Guo-Yu Yang*, A series of organic–inorganic hybrids based on lanthanide-substituted Dawson-type phosphotungstate dimers and copper–en linkers, CrystEngComm, 2014, 16, 2230–2238.

著作:

1.      《无机化学实验》, ISBN 978-7-122-08934-2,化学工业出版社,20108月,参编约6万字。

2.      《无机及分析化学》,ISBN 978-7-308-09015-3,浙江大学出版社,20119月,参编约7万字。

3. 《实用仪器分析教程》, ISBN 978-7-308-12144-6, 浙江大学出版社,20139月,副主编,8.1万字。

 

项目:

1. 有机金属与稀土共嵌入的含亚族价杂原子多钨氧酸盐有机-无机复合材料的设计合成及光磁性质研究(21771052), 国家自然科学基金,65万,主持,2018.1–2021.12

2. 多核稀土取代含As, Sb, Bi, Se, Te杂原子多钨氧酸盐纳米簇的设计合成及抗癌活性研究(21571048), 国家自然科学基金,70万,主持,2016.1–2019.12

3. 有机-无机杂化钨氧簇基材料的制备、铁电及磁性研究(21101055),国家自然科学基金,30万,主持,2012.1–2014.12

4. 有机功能配体调控的多核稀土离子嵌入的杂多钨氧簇材料的制备、结构、发光性能及发光机理研究(174100510016), 河南省科技创新人才杰出青年基金项目, 30万,主持,2017.1–2018.12,在研。

5. 高核稀土取代多钨氧酸盐纳米簇合物的设计、制备及抗癌活性研究(16HASTIT001), 河南省高校科技创新人才支持计划, 30万,主持,2016.1–2018.12

6. 多核稀土取代多钨氧酸盐纳米簇的设计合成及抗癌活性研究(20160016), 结构化学国家重点实验室科学基金, 2万,主持,2016.1–2018.12

7.     含孤对电子杂原子的多钨氧酸盐3d-4f异金属磁性材料的设计合成和性能研究(142300410451),河南省基础与前沿技术研究计划项目,5万,主持,2014.1-2016.12

8. 有机-无机杂化多钨氧酸盐基3d-4f异金属衍生材料的制备、铁电及磁性研究(201104392),中国博士后特别资助,10万,主持,2011.10–2013.1

9. 无机-有机杂化钨-氧簇基铁电和磁性材料的制备与性能研究(20120013),结构化学国家重点实验室开放基金,3万,主持,2012.1–2014.12

10. 多金属氧酸盐基3d-4f金属衍生物的合成及荧光磁性研究(20100470996),中国博士后科学基金,3万,主持,2010.8–2013.1

11. 稀土簇与缺位多金属氧酸盐簇的组装化学及相关性能研究(092300410119),河南省科技厅自然科学基金,3万,主持,2009.1–2011.12

12. 杂化钨氧簇基材料的制备和铁电磁性研究(2012GGJS-027),河南省高等学校青年骨干教师资助项目,4万,主持,2012.10–2015.10

13. 有机-无机杂化的过渡金属取代多钨氧酸盐的制备和磁性研究(2010B150006),河南省教育厅自然科学基金,0万,主持,2010.05–2012.12

14. 杂多钨氧酸盐基有机-无机杂化压电材料的制备及相关性能研究(XXJC20140001),河南大学新兴交叉及特色学科培育计划,25万,主持,2014.05–2018.05

15. 稀土簇与缺位多金属氧酸盐簇的组装化学及相关性能研究(2008YBZR010), 河南大学自然科学基金,0.5万,主持,2009.1–2010.12

16. 多金属氧酸盐基的稀土簇荧光材料研究, 2009年河南大学大学生创新性实验计划项目,0.2万,指导,2009.6–2011.5

17. 多金属氧酸盐基3d-4f异金属衍生物的合成及荧光磁性研究, 2012年河南大学大学生创新性实验计划项目,0.2万,指导,2012.6–2014.5

18. 杂化钨氧簇基材料的制备、铁电及磁性研究,2013年河南大学大学生创新性实验计划项目,0.2万,指导,2013.6–2015.5

19. /锑杂原子多钨氧酸盐过渡-稀土异金属磁性材料的设计合成和性能研究,2014年河南大学大学生创新性实验计划项目,0.2万,指导,2014.6–2016.5

20. 杂多钼氧酸盐3d-4f异金属衍生材料的设计合成及其对有机染料光降解性能研究, 2015年河南大学大学生创新性实验计划项目(同时为2015年地方高校国家级大学生创新创业训练计划项目)0.3万,指导,2015.6–2017.5

21. 有机-无机杂化多核稀土离子嵌入的多钨氧簇材料的设计、合成和荧光性能研究,2016年河南大学大学生创新性实验计划项目(同时为2016年地方高校国家级大学生创新创业训练计划项目)0.3万,指导,2016.6–2018.5

22. 有机金属与稀土共嵌入多钨氧酸盐有机-无机复合材料的设计合成及光磁性质研究,2017年河南大学大学生创新性实验计划项目,0.2万,指导,2017.6–2019.5

23. 有机–无机高核稀土取代杂多钨氧酸盐材料的合成、结构和发光性能及机理研究,2018年河南大学大学生创新性实验计划项目(同时为2018年地方高校国家级大学生创新创业训练计划项目)0.3万,指导,2018.6–2020.5

获奖成果:

1. /钼氧簇分子基功能材料结构设计及性能调控, 河南省教育厅科技成果一等奖,排名第一,20185月。

2. 多酸稀土衍生物的合成、结构及性质研究,河南省科学技术进步二等奖,排名第四,201612月。

3. Combination between lacunary polyoxometalates and high-nuclear transition metal   clusters under hydrothermal conditions: first (3,6)-connected framework constructed from sandwich-type polyoxometalate building blocks containing a novel {Cu8} cluster,河南省第十届自然科学优秀学术论文一等奖,排名第一,20104月。

4. Two-dimensional extended (4,4)-topological network constructed from tetra-NiII- substituted sandwich-type Keggin polyoxometalate building blocks and NiII-organic cation bridges河南省第十届自然科学优秀学术论文一等奖,排名第一,20104月。

5. Hydrothermal syntheses, crystal structures and properties of 0-D, 1-D and 2-D organic–inorganic hybrid borotungstates constructed from Keggin-type heteropolyanion [α-BW12O40]5-河南省首届自然科学学术奖河南省自然科学优秀学术论文二等奖,排名第一,20119月。

6. A combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. Part II: From double cluster, dimer, and tetramer to three-dimensional frameworks,河南省教育厅优秀科技论文一等奖,排名第一,20106月。

7. Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions: first 65·8 CdSO4-type 3-D framework built by hexa-CuII sandwiched polyoxotungstates,河南省教育厅优秀科技论文一等奖,排名第一,20126月。

8. Combination of lacunary polyoxometalates and high-nuclear transition-metal clusters under hydrothermal conditions. 5. A novel tetrameric cluster of [{FeIIFeIII123-OH)12 4-PO4)4} (B-α-PW9O34)4]22-, 河南省教育厅优秀科技论文一等奖,排名第一,20126月。

9. Novel polyoxometalate hybrids containing copper-lanthanide heterometallic germanotungstate / lanthanide-germanotungstate fragments河南省第二届自然科学学术奖河南省自然科学优秀学术论文二等奖,排名第一,201312月。

10. Two 1-D multi-nickel substituted arsenotungstate aggregates河南省第二届自然科学学术奖河南省自然科学优秀学术论文二等奖,排名第一,201312月。

11. Two organic–inorganic hybrid 1-D and 3-D polyoxotungstates constructed from hexa-CuII substituted sandwich-type arsenotungstate units河南省第二届自然科学学术奖河南省自然科学优秀学术论文三等奖,排名第一,201312月。

12. Tetrahedral Polyoxometalate Nanoclusters with Tetrameric Rare-Earth Cores and Germanotungstate Vertexes, 河南省第三届自然科学学术奖—河南省自然科学优秀学术论文二等奖,排名第一,201512月。

13. Rectangle versus Square Oxalate- Connective Tetralanthanide Cluster Anchored in Lacunary Lindqvist Isopolytungstates: Syntheses, Structures, and Properties,河南省第三届自然科学学术奖—河南省自然科学优秀学术论文三等奖,排名第一,201512月。

14. 有机-无机杂化过渡-稀土异金属取代锗钨酸盐晶态储氢材料及其制备方法,专利号:ZL 2012 1 0423422.0, 中国专利局授予的发明专利, 授权时间:20144月,排名:第一。

15. (2-乙酰吡嗪基)硫代缩二氨基脲及其铋(III)配合物的制备方法及应用,专利号:ZL 2012 1 0493229.4, 中国专利局授予的发明专利, 授权时间:20149月,排名:第一

16. 一种镝-异烟酸包含的Waugh锰钼酸盐及其制备方法和应用,专利号:ZL 2016 1 0641621.7, 中国专利局授予的发明专利, 授权时间:20182月,排名:第二

17. -铕异金属取代砷钨酸盐及其制备方法和应用,专利号:ZL 2015 1 0035099.3, 中国专利局授予的发明专利, 授权时间:20164月,排名:第四

18. 一种十核铽取代砷钨氧酸盐纳米簇合物及其制备方法和应用,专利号:ZL 2015 1 0787718.4, 中国专利局授予的发明专利, 授权时间:201712月,排名:第四

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