系别:化学系
职称:河南大学“杰出人才特区支持计划”第四层次特聘教授
邮箱:zycao@henu.edu.cn
个人简介:
曹中艳,男,玛丽·居里协会会员,1988年出生于安徽亳州,任职于河南大学化学化工学院,特聘教授。已发表第一作者和通讯作者SCI论文17篇(含共同一作四篇),包括自然子刊Nature Commun.1篇,J. Am. Chem. Soc.1篇,Acc. Chem. Res.1篇,Angew. Chem., Int. Ed.1篇;其中14篇为JCR一区,14篇论文影响因子大于5;以第二作者在Chem. Rev., J. Am. Chem. Soc.和Angew. Chem. Int. Ed.等顶级期刊发表SCI论文7篇;共发表SCI论文40余篇,论文他引约2000次,有4篇论文入选ESI高被引用论文,1篇为热点论文;以第一、二作者身份撰写英文专著各两章,以及中文专著一节,共计四万余字;授权中国发明专利两项。曾获得国家研究生奖学金、宝钢奖学金、华师大学术新人奖、入选优博培育计划,以及欧盟玛丽·居里奖学金等。
主要教育经历:
2010年9月-2015年11月,华东师范大学,化学化工学院,直博,理学博士 (导师:周剑教授)
2006年9月-2010年7月,华东师范大学,化学化工学院,理学学士(本科毕设导师:麻生明教授,刘宇博士)
主要研究工作经历:
2020年11月至今,河南大学,化学化工学院,硕士生导师,河南大学“杰出人才特区支持计划”第四层次特聘教授
2019年8月-2020年11月,浙江工业大学,化学工程学院
2018年12月-2019年8月,新加坡南洋理工大学,博士后,合作导师:周建荣教授
2016年5月-2018年8月,西班牙ICIQ研究所,博士后,合作导师:Paolo Melchiorre教授
主要研究方向:
不对称催化,光、电催化,自由基化学,绿色高分子材料合成
承担基金:
河南大学“杰出人才特区支持计划”第四层次科研启动基金,2020-2025
欧盟玛丽·居里基金,2016-2018
学术兼职:
中国化学会会员、玛丽居里协会会员、Frontiers in Chemistry、RSC Advances和Frontiers in Catalysis杂志青年编委
部分同行评议论文 (他引次数约 2000; H指数 = 20)
1. (1-Selenocyanatoethyl)benzene: A Selenocyanation Reagent for Site-Selective Selenocyanation of Inert Alkyl C(sp3)−H Bonds
Fei Yu, Chuang Li, Chuangye Wang, Hongwei Zhang,* and Zhong-Yan Cao*, Org. Lett., 2021, DOI: 10.1021/acs.orglett.1c02564
2. Catalytic Asymmetric Synthesis of Monofluoroalkenes and gem-Difluoroalkenes: Advances and Perspectives
X. Zhang, Y. Cheng, X. Zhao, Z.-Y. Cao*, X. Xiao*, Y. Xu*, Org. Chem. Front. 2021, 8, 2315. (IF = 5.15)
3. Copper-Catalyzed Remote Direct Thiocyanation of Alkyl C(sp3)–H Bonds
Q. Wang, P. Tian, Z.-Y. Cao*, H. Zhang*, C. Jiang, Adv. Synth. Catal. 2020, 362, 3851. (IF = 5.86)
4. Activating pronucleophiles with high pKa values: Chiral organo-superbases.
Y.-H. Wang‡, Z.-Y. Cao‡, Q.-H. Li, G.-Q. Lin, J. Zhou*, P. Tian* Angew. Chem., Int. Ed. 2020, 59, 8004.
(IF = 12.96) (‡co-first authors)
5. Enantioselective radical conjugate additions driven by the photoactivity of an intramolecular iminium-ion-based EDA complex.
Z.-Y. Cao, T. Ghosh, P. Melchiorre*, Nature Commun. 2018, 9 (3274), DOI: 10.1038/s41467-018-05375-2. (IF = 12.12)
6. Development of synthetic methodologies via catalytic enantioselective synthesis of 3,3-disubstituted oxindoles.
Z.-Y. Cao, F. Zhou, J. Zhou*, Acc. Chem. Res., 2018, 51, 1443. (IF = 20.83) (ESI高被引用论文,热点论文)
7. Highly stereoselective olefin cyclopropanation of diazooxindoles catalyzed by a C2-symmetric spiroketal bisphosphine/Au(I) complex. (ESI高被引用论文)
Z.-Y. Cao, X. Wang, C. Tan, X.-L. Zhao, J. Zhou*, K. Ding, J. Am. Chem. Soc. 2013‚ 135‚ 8197. (IF = 14.61)
8. Catalytic enantioselective synthesis of cyclopropanes featuring vicinal all-carbon quaternary stereocenters with a CH2F group; study of the influence of C–F⋯H–N interactions on reactivity. (‡co-first authors)
Z.-Y. Cao‡, W. Wang‡, K. Liao, X. Wang, J. Zhou*, J. Ma*, Org. Chem. Front. 2018, 5, 2960. (IF = 5.16)
9. Sequential Au(I)/chiral tertiary amine catalysis: a tandem C–H functionalization of anisoles or a thiophene/asymmetric Michael addition sequence to quaternary oxindoles. (‡co-first authors)
Z.-Y. Cao‡, Y.-L. Zhao‡, J. Zhou*, Comm. Commun. 2016, 52, 2537. (IF = 6.00)
10. Asymmetric sequential Au(I)/chiral tertiary amine catalysis: an enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles. (‡co-first authors)
Y.-L. Zhao‡, Z.-Y. Cao‡, X.-P. Zeng, J.-M. Shi, Y.-H. Yu, J. Zhou*, Comm. Commun. 2016, 52, 3943. (IF = 6.00)
11. A highly diastereo- and enantioselective Hg(II)-catalyzed cyclopropanation of diazooxindoles and alkenes
Z.-Y. Cao, F. Zhou, Y.-H. Yu, J. Zhou*, Org. Lett. 2013‚ 15, 42. (Highlighted by Synfacts 2013‚ 415.) (IF = 6.09)
12. A Hg(ClO4)2•3H2O catalyzed Sakurai-Hosomi allylation of isatins and isatin ketoimines using allyltrimethylsilane.
Z.-Y. Cao‚ Y. Zhang‚ C.-B. Ji‚ J. Zhou*‚ Org. Lett. 2011‚ 13‚ 6398. (IF = 6.09)
13. A highly enantioselective Hg(II)-catalyzed Sakurai–Hosomi reaction of isatins with allyltrimethylsilanes.
Z.-Y. Cao, J.-S. Jiang, J. Zhou*, Org. Biomol. Chem. 2016, 14, 5500. (Invited paper for New Talent Issue) (IF = 3.41)
14. Catalytic asymmetric synthesis of 3,3-disubstituted oxindoles: diazooxindole joins the field.
Z.-Y. Cao, Y.-H. Wang, X.-P. Zeng, J. Zhou*, Tetrahedron Lett. 2014, 55, 2571. (Invited Digest Paper) (IF = 2.28)
15. Recent advances in the use of chiral metal complexes with achiral ligands for application in asymmetric catalysis.
Z.-Y. Cao, W. D. G. Brittain, J. S. Fossey, F. Zhou*, Catal. Sci. Technol. 2015, 5, 3341. (Cover Paper) (IF = 5.72)
16. Catalytic asymmetric synthesis of spirocyclopropyl oxindoles: organocatalysis versus transition metal catalysis.
Z.-Y. Cao, J. Zhou*, Org. Chem. Front. 2015, 2, 849. (IF = 5.16)
17. Carbon tetrabromide.
Z.-Y. Cao, Synlett, 2013, 24, 889. (IF = 2.00)
18. Highly stereoselective Gold-catalyzed coupling of diazo reagents and fluorinated enol silyl ethers to tetrasubstituted alkenes
F.-M. Liao, Z.-Y. Cao, J.-S. Yu, J. Zhou*, Angew. Chem., Int. Ed. 2017, 56, 2459. (IF = 12.96)
19. Catalytic enantioselective desymmetrization reactions to all-carbon quaternary stereocenters. (ESI高被引用论文)
X.-P. Zeng, Z.-Y. Cao, Y.-H. Wang, F. Zhou, J. Zhou*, Chem. Rev. 2016, 116, 7330. (IF = 52.76)
20. Activation of chiral (Salen)AlCl complex by phosphorane for highly enantioselective cyanosilylation of ketones and enones
X.-P. Zeng, Z.-Y. Cao, X. Wang, L. Chen, F. Zhou, F. Zhu, C.-H. Wang, J. Zhou*, J. Am. Chem. Soc. 2016‚ 138‚ 416.
(IF = 14.61)
21. Catalytic Enantioselective Construction of Spiro Quaternary Carbon Stereocenters. (ESI高被引用论文)
P.-W. Xu, J.-S. Yu, C. Chen, Z.-Y. Cao, F. Zhou, J. Zhou*, ACS Catal. 2019, 9, 1820. (IF = 12.35)
22. Diastereo- and enantioselective [3+3] cycloaddition of spirocyclopropyl oxindoles using both aldonitrones and ketonitrones. P.-W. Xu, J.-K. Liu, L. Shen, Z.-Y. Cao, X.-L. Zhao, J. Yan*, J. Zhou*
Nature Commun. 2017, 8 (1619), DOI: 10.1038/s41467-017-01451-1. (IF = 12.12)
23. Nucleophilic difluoromethylenation of ketones using diethyl (difluoro(trimethylsilyl)methyl)phosphonate mediated by 18-Crown-6 ether/KOAc.
Y.-H. Wang, Z.-Y. Cao, J. Zhou*, J. Org. Chem. 2016, 81, 7807. (IF = 4.34)
24. A catalyst-free, one-pot three-component aminomethylation of alpha-substituted nitroacetates: theoretical and experimental studies into the rate-accelerating effects of the solvent methanol.
C.-B. Ji, Z.-Y. Cao, X. Wang,* D.-Y. Wu, J. Zhou*, Chem. Asian J. 2013, 8, 877. (IF = 4.06)
25. A highly efficient Friedel-Crafts reaction of 3-hydroxyoxindoles and aromatic compounds to 3,3-diaryl and 3-alkyl-3-aryloxindoles catalyzed by Hg(ClO4)2•3H2O.
F. Zhou‚ Z.-Y. Cao‚ J. Zhang‚ H. B. Yang‚ J. Zhou*‚ Chem. Asian J. 2012‚ 7‚ 233. (IF = 4.06)
26. Hydroxymethylation of α-substituted nitroacetates.
C.-B. Ji‚ Y.-L. Liu‚ Z.-Y. Cao‚ Y.-Y. Zhang‚ J. Zhou*, Tetrahedron Lett. 2011‚ 52‚ 6118. (IF = 2.28)
学术专著 (四章英文专著和一节中文专著)
27. Z.-Y. Cao, F. Zhu, J. Zhou*, Chapter 2, P37-158; L. Chen, Z.-Y. Cao, J. Zhou*, Chapter 5, P373-410; Z.-Y. Cao, J. Zhou*, Chapter 7, P475-500, “Multicatalyst System in Asymmetric Catalysis”, John Wiley & Sons Inc., New York, 2014.
28. 周剑、曹中艳,丁奎岭手性螺缩酮双膦配体(SKP), p748, 黄培强主编,有机人名反应、试剂与规则,第二版,化学工业出版社,2019.
29. Y.-H. Wang, Z.-Y. Cao, J. Zhou*, “Gold Catalysis in the Synthesis of Natural Products: Heterocycle Construction via Direct C-X-Bond-Forming Reactions”, P1-35, Au-Catalyzed Synthesis and Functionalization of Heterocycles, Springer Berlin Heidelberg, 2016.
授权专利
30. 周剑, 曹中艳 中国发明专利, ZL201110024744.3 2012.
31. 周剑,周锋,刘亮,曹中艳 中国发明专利,ZL201110022559.0 2011.