杰出人才特区第四层次人才

曹中艳

发布时间:2017-04-16
浏览次数:
来源: 管理员

系别:化学系

职称:河南大学“杰出人才特区支持计划”第四层次特聘教授

邮箱:zycao@henu.edu.cn

 

个人简介:

曹中艳,男,玛丽·居里协会会员,1988年出生于安徽亳州,任职于河南大学化学化工学院,特聘教授。已发表第一作者和通讯作者SCI论文17篇(含共同一作四篇),包括自然子刊Nature Commun.1篇,J. Am. Chem. Soc.1篇,Acc. Chem. Res.1篇,Angew. Chem., Int. Ed.1篇;其中14篇为JCR一区,14篇论文影响因子大于5;以第二作者在Chem. Rev., J. Am. Chem. Soc.Angew. Chem. Int. Ed.等顶级期刊发表SCI论文7篇;共发表SCI论文40余篇,论文他引约2000次,有4篇论文入选ESI高被引用论文,1篇为热点论文;以第一、二作者身份撰写英文专著各两章,以及中文专著一节,共计四万余字;授权中国发明专利两项。曾获得国家研究生奖学金、宝钢奖学金、华师大学术新人奖、入选优博培育计划,以及欧盟玛丽·居里奖学金等。

 

主要教育经历:

20109-201511月,华东师范大学,化学化工学院,直博,理学博士 (导师:周剑教授)

20069-20107月,华东师范大学,化学化工学院,理学学士(本科毕设导师:麻生明教授,刘宇博士)

主要研究工作经历:

202011月至今,河南大学,化学化工学院,硕士生导师,河南大学“杰出人才特区支持计划”第四层次特聘教授

20198-202011月,浙江工业大学,化学工程学院

201812-20198月,新加坡南洋理工大学,博士后,合作导师:周建荣教授

20165-20188月,西班牙ICIQ研究所,博士后,合作导师:Paolo Melchiorre教授

主要研究方向:

不对称催化,光、电催化,自由基化学,绿色高分子材料合成

承担基金:

河南大学“杰出人才特区支持计划”第四层次科研启动基金,2020-2025

欧盟玛丽·居里基金,2016-2018

 

学术兼职:

中国化学会会员、玛丽居里协会会员、Frontiers in ChemistryRSC AdvancesFrontiers in Catalysis杂志青年编委

 

部分同行评议论文 (他引次数约 2000; H指数 = 20)

1.        (1-Selenocyanatoethyl)benzene: A Selenocyanation Reagent for Site-Selective Selenocyanation of Inert Alkyl C(sp3)−H Bonds

Fei Yu, Chuang Li, Chuangye Wang, Hongwei Zhang,* and Zhong-Yan Cao*, Org. Lett., 2021, DOI: 10.1021/acs.orglett.1c02564

2.        Catalytic Asymmetric Synthesis of Monofluoroalkenes and gem-Difluoroalkenes: Advances and Perspectives

X. Zhang, Y. Cheng, X. Zhao, Z.-Y. Cao*, X. Xiao*, Y. Xu*, Org. Chem. Front. 2021, 8, 2315.  (IF = 5.15)

3.        Copper-Catalyzed Remote Direct Thiocyanation of Alkyl C(sp3)–H Bonds

Q. Wang, P. Tian, Z.-Y. Cao*, H. Zhang*, C. Jiang, Adv. Synth. Catal. 2020, 362, 3851. (IF = 5.86)

4.        Activating pronucleophiles with high pKa values: Chiral organo-superbases.

Y.-H. Wang‡, Z.-Y. Cao‡, Q.-H. Li, G.-Q. Lin, J. Zhou*, P. Tian* Angew. Chem., Int. Ed. 2020, 59, 8004.       

 (IF = 12.96)       (‡co-first authors)

5.        Enantioselective radical conjugate additions driven by the photoactivity of an intramolecular iminium-ion-based EDA complex.

Z.-Y. Cao, T. Ghosh, P. Melchiorre*, Nature Commun. 2018, 9 (3274), DOI: 10.1038/s41467-018-05375-2.  (IF = 12.12)

6.        Development of synthetic methodologies via catalytic enantioselective synthesis of 3,3-disubstituted oxindoles.

Z.-Y. Cao, F. Zhou, J. Zhou*, Acc. Chem. Res., 2018, 51, 1443.  (IF = 20.83)    (ESI高被引用论文,热点论文)

7.        Highly stereoselective olefin cyclopropanation of diazooxindoles catalyzed by a C2-symmetric spiroketal bisphosphine/Au(I) complex.                                      (ESI高被引用论文)

Z.-Y. Cao, X. Wang, C. Tan, X.-L. Zhao, J. Zhou*, K. Ding, J. Am. Chem. Soc. 2013‚ 135‚ 8197.         (IF = 14.61)

8.        Catalytic enantioselective synthesis of cyclopropanes featuring vicinal all-carbon quaternary stereocenters with a CH2F group; study of the influence of C–FH–N interactions on reactivity.                    (‡co-first authors)

Z.-Y. Cao‡, W. Wang‡, K. Liao, X. Wang, J. Zhou*, J. Ma*, Org. Chem. Front. 2018, 5, 2960.          (IF = 5.16)

9.        Sequential Au(I)/chiral tertiary amine catalysis: a tandem C–H functionalization of anisoles or a thiophene/asymmetric Michael addition sequence to quaternary oxindoles.                                  (‡co-first authors)

Z.-Y. Cao‡, Y.-L. Zhao‡, J. Zhou*, Comm. Commun. 2016, 52, 2537. (IF = 6.00)

10.      Asymmetric sequential Au(I)/chiral tertiary amine catalysis: an enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles.                             (‡co-first authors) 

Y.-L. Zhao‡, Z.-Y. Cao‡, X.-P. Zeng, J.-M. Shi, Y.-H. Yu, J. Zhou*, Comm. Commun. 2016, 52, 3943. (IF = 6.00)

11.      A highly diastereo- and enantioselective Hg(II)-catalyzed cyclopropanation of diazooxindoles and alkenes

Z.-Y. Cao, F. Zhou, Y.-H. Yu, J. Zhou*, Org. Lett. 2013‚ 15, 42.        (Highlighted by Synfacts 2013‚ 415.) (IF = 6.09)

 

12.      A Hg(ClO4)2•3H2O catalyzed Sakurai-Hosomi allylation of isatins and isatin ketoimines using allyltrimethylsilane.

Z.-Y. Cao‚ Y. Zhang‚ C.-B. Ji‚ J. Zhou*‚ Org. Lett. 2011‚ 13‚ 6398.             (IF = 6.09)

13.      A highly enantioselective Hg(II)-catalyzed Sakurai–Hosomi reaction of isatins with allyltrimethylsilanes.

Z.-Y. Cao, J.-S. Jiang, J. Zhou*, Org. Biomol. Chem. 2016, 14, 5500. (Invited paper for New Talent Issue) (IF = 3.41)

14.      Catalytic asymmetric synthesis of 3,3-disubstituted oxindoles: diazooxindole joins the field.

Z.-Y. Cao, Y.-H. Wang, X.-P. Zeng, J. Zhou*, Tetrahedron Lett. 2014, 55, 2571. (Invited Digest Paper) (IF = 2.28)

15.      Recent advances in the use of chiral metal complexes with achiral ligands for application in asymmetric catalysis.

Z.-Y. Cao, W. D. G. Brittain, J. S. Fossey, F. Zhou*, Catal. Sci. Technol. 2015, 5, 3341.  (Cover Paper) (IF = 5.72)

16.      Catalytic asymmetric synthesis of spirocyclopropyl oxindoles: organocatalysis versus transition metal catalysis.

Z.-Y. Cao, J. Zhou*, Org. Chem. Front. 2015, 2, 849.                         (IF = 5.16)

17.      Carbon tetrabromide. 

Z.-Y. Cao, Synlett, 2013, 24, 889.                               (IF = 2.00)

18.      Highly stereoselective Gold-catalyzed coupling of diazo reagents and fluorinated enol silyl ethers to tetrasubstituted alkenes

F.-M. Liao, Z.-Y. Cao, J.-S. Yu, J. Zhou*, Angew. Chem., Int. Ed. 2017, 56, 2459.                    (IF = 12.96)

19.      Catalytic enantioselective desymmetrization reactions to all-carbon quaternary stereocenters.  (ESI高被引用论文)

X.-P. Zeng, Z.-Y. Cao, Y.-H. Wang, F. Zhou, J. Zhou*, Chem. Rev. 2016, 116, 7330.           (IF = 52.76) 

20.      Activation of chiral (Salen)AlCl complex by phosphorane for highly enantioselective cyanosilylation of ketones and enones

X.-P. Zeng, Z.-Y. Cao, X. Wang, L. Chen, F. Zhou, F. Zhu, C.-H. Wang, J. Zhou*, J. Am. Chem. Soc. 2016‚ 138‚ 416.

(IF = 14.61)

21.  Catalytic Enantioselective Construction of Spiro Quaternary Carbon Stereocenters.         (ESI高被引用论文)

P.-W. Xu, J.-S. Yu, C. Chen, Z.-Y. Cao, F. Zhou, J. Zhou*, ACS Catal. 2019, 9, 1820.  (IF = 12.35)

22.  Diastereo- and enantioselective [3+3] cycloaddition of spirocyclopropyl oxindoles using both aldonitrones and ketonitrones. P.-W. Xu, J.-K. Liu, L. Shen, Z.-Y. Cao, X.-L. Zhao, J. Yan*, J. Zhou*

Nature Commun. 2017, 8 (1619), DOI: 10.1038/s41467-017-01451-1.  (IF = 12.12)

23.  Nucleophilic difluoromethylenation of ketones using diethyl (difluoro(trimethylsilyl)methyl)phosphonate mediated by 18-Crown-6 ether/KOAc.

Y.-H. Wang, Z.-Y. Cao, J. Zhou*, J. Org. Chem. 2016, 81, 7807.               (IF = 4.34) 

24.  A catalyst-free, one-pot three-component aminomethylation of alpha-substituted nitroacetates: theoretical and experimental studies into the rate-accelerating effects of the solvent methanol.

C.-B. Ji, Z.-Y. Cao, X. Wang,* D.-Y. Wu, J. Zhou*, Chem. Asian J. 2013, 8, 877.  (IF = 4.06)  

25.      A highly efficient Friedel-Crafts reaction of 3-hydroxyoxindoles and aromatic compounds to 3,3-diaryl and 3-alkyl-3-aryloxindoles catalyzed by Hg(ClO4)2•3H2O.

F. Zhou‚ Z.-Y. Cao‚ J. Zhang‚ H. B. Yang‚ J. Zhou*‚ Chem. Asian J. 2012‚ 7‚ 233.  (IF = 4.06)     

26.      Hydroxymethylation of α-substituted nitroacetates.

C.-B. Ji‚ Y.-L. Liu‚ Z.-Y. Cao‚ Y.-Y. Zhang‚ J. Zhou*, Tetrahedron Lett. 2011‚ 52‚ 6118.        (IF = 2.28) 

学术专著 (四章英文专著和一节中文专著)

27.      Z.-Y. Cao, F. Zhu, J. Zhou*, Chapter 2, P37-158; L. Chen, Z.-Y. Cao, J. Zhou*, Chapter 5, P373-410; Z.-Y. Cao, J. Zhou*, Chapter 7, P475-500, “Multicatalyst System in Asymmetric Catalysis”, John Wiley & Sons Inc., New York, 2014.

28.      周剑、曹中艳,丁奎岭手性螺缩酮双膦配体(SKP), p748, 黄培强主编,有机人名反应、试剂与规则,第二版,化学工业出版社,2019.

29.      Y.-H. Wang, Z.-Y. Cao, J. Zhou*, “Gold Catalysis in the Synthesis of Natural Products: Heterocycle Construction via Direct C-X-Bond-Forming Reactions”, P1-35, Au-Catalyzed Synthesis and Functionalization of Heterocycles, Springer Berlin Heidelberg, 2016.

授权专利

30.      周剑, 曹中艳 中国发明专利, ZL201110024744.3 2012.

31.      周剑,周锋,刘亮,曹中艳 中国发明专利,ZL201110022559.0 2011.

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