熊恒英

发布时间:2017-10-20
浏览次数:
来源: 管理员

           WechatIMG462副本.jpeg

系别:化学系

传真:0378-3881589

邮箱:xionghengying@vip.henu.edu.cn, xionghengying@163.com

个人简介:

熊恒英博士,硕士生导师,法国鲁昂国立应用科学学院(INSA-Rouen)化学专业博士,河南大学黄河学者。近年来 Angewandte Chemie International Edition, Chemistry A European Journal, Journal of Organic Chemistry, Chemical Communications等国际期刊上发表论文11篇,其中以第一作者发表文章6篇,他引共近300余次。

主要教育经历:

2013年10月-2017年3月,法国鲁昂国立应用科学学院(INSA-RouenUMR 6014-COBRA有机化学,博士 (导师:Xavier Pannecoucke教授,Dominique Cahard博士,Tatiana Besset博士)

2010年9月-2013年7月,天津大学,有机化学,理学硕士(导师:马军安教授)

2006年9月-2010年7月,内江师范学院,化学专业,理学学士

主要研究工作经历:

2018年3月至今,河南大学化学化工学院,硕士生导师,河南大学黄河学者

主要研究方向:

惰性键活化,有机功能分子的合成及应用

承担基金:

河南大学黄河学者科研启动基金(60万)2018-2022年

科研成果:

1.                     H.-Y. Xiong, A. Bayle, X. Pannecoucke, T. Besset, “An Electrophilic Reagent for the Direct Introduction of the SCF2PO(OEt)2 Group to Molecules”.

   Angew. Chem. Int. Ed. 2016, 55, 13490.

2.                     H.-Y. Xiong, X. Pannecoucke, T. Besset. “Recent Advances in the Synthesis of SCF2H- and SCF2FG Containing Molecules”.

Chem. Eur. J. 2016, 22, 16734.

3.                     H.-Y. Xiong, X. Pannecoucke, T. Besset. “Oxidative trifluoromethylthiolation and thiocyanation of amines: a general approach to N–S bond formation”.

Org. Chem. Front. 2016, 3, 620.  

4.                     H.-Y. Xiong, D. Cahard, X. Pannecoucke, T. Besset. “Pd-Catalyzed Directed Chlorination of Unactivated C(sp3)–H Bonds at Room Temperature”.

Eur. J. Org. Chem. 2016, 3625. (Hottest articles in New Synthetic Methods, Wiley).

5.                     H.-Y. Xiong, T. Besset, D. Cahard, X. Pannecoucke. “Palladium(II)-Catalyzed Directed Trifluoromethylthiolation of Unactivated C(sp3)–H Bonds”.

   J. Org. Chem. 2015, 80, 4204.

6.                     H.-Y. Xiong, Z.-Y. Yang, Z. Chen, J.-L. Zeng, J. Nie, J.-A. Ma. “Copper-Catalyzed One-Pot Denitrogenative-Dehydrogenative-Decarboxylative Coupling of β-Ketoacids with Trifluorodiazoethane: Facile Access to Trifluoromethylated Aldol Products”.

Chem. Eur. J. 2014, 20, 8325.

7.                     M.-C. Belhomme, D. Dru, H.-Y. Xiong, D. Cahard, T. Besset, T. Poisson, X. Pannecoucke. “Copper Mediated Direct Functionalization of Unsaturated C–C Bonds using BrCF2CO2Et: a Straightforward Access to Highly Valuable Difluoromethylated Alkenes”.

Synthesis 2014, 46, 1859.

8.                     W.-T. Meng, Y. Zheng, J. Nie, H.-Y. Xiong, J.-A. Ma. “Organocatalytic Asymmetric One-Pot Sequential Conjugate Addition/Dearomative Fluorination: Synthesis of Chiral Fluorinated Isoxazol-5(4H)-ones”.

J. Org. Chem. 2013, 78, 559.

9.                     Y. Zheng, H.-Y. Xiong, M.-Q. Hua, J.-A. Ma. “Biomimetic catalytic enantioselective decarboxylative aldol reaction of β-ketoacids with trifluoromethyl ketones”.

Chem. Commun. 2012, 48, 4308.

10.                X.-J. Li, H.-Y. Xiong, M.-Q. Hua, J. Nie, Y. Zheng, J.-A. Ma. “Convenient and efficient decarboxylative aldol reaction of malonic acid half esters with trifluoromethyl ketones”. Tetrahedron Lett. 2012, 53, 2117.

11.                J. Nie, M.-Q. Hua, H.-Y. Xiong, Y. Zheng, J.-A. Ma. “Asymmetric phase-transfer-catalyzed conjugate addition of glycine imine to exocyclic α,β-unsaturated ketones construction of polycyclic imines containing three stereocenters”.

J. Org. Chem. 2012, 77, 420.

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